Modified boron subphthalocyanines with stable electrochemistry and tuneable bandgaps.
نویسندگان
چکیده
The synthesis of boron subphthalocyanines (BsubPc) from modified phthalonitriles is reported. The BsubPcs have intense red-shifted absorption compared to normal BsubPcs and readily tuneable optoelectronic properties including enhanced electrochemical stability and the presence of up to two reversible electrochemical reductions.
منابع مشابه
Synthesis and spectroscopic properties of chiral binaphthyl-linked subphthalocyanines.
Chiral binaphthyl-linked subphthalocyanines (SubPcs) (1) have been prepared by the cyclotrimerization reaction of a phthalonitrile linked with (R)- and (S)-2,2'-binaphthyl in the presence of BCl3, and characterized by various spectroscopies including NMR, electronic absorption, CD, and MCD, as well as electrochemistry.
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عنوان ژورنال:
- Dalton transactions
دوره 42 36 شماره
صفحات -
تاریخ انتشار 2013